Properties
Missing imageTitanium(IV)_oxide.jpg Titanium(IV) oxide |
| General |
|---|
| Name |
Titanium(IV) oxide |
| Chemical formula |
TiO2 |
| Appearance |
White solid |
|
Physical
|
| Formula weight |
79.9 amu |
| Melting point |
~2103 K (1830 °C) |
| Boiling point |
~2773 K (2500 °C) |
| Density |
4.2 ×103 kg/m3 |
| Crystal structure |
rutile |
| Solubility |
insoluble |
|
Thermochemistry
|
| ΔfH0gas |
-249 kJ/mol |
| ΔfH0liquid |
-879 kJ/mol |
| ΔfH0solid |
-944 kJ/mol |
| S0solid |
51 J/mol·K |
|
Safety
|
| Ingestion |
Low hazard for accidental ingestion. |
| Inhalation |
Irritating, dangerous in the long term. |
| Skin |
Low hazard. |
| Eyes |
Low hazard. |
| More info |
Hazardous Chemical Database (http://ull.chemistry.uakron.edu/erd/chemicals1/8/7743.html) |
|
SI units were used where possible. Unless otherwise stated, standard conditions were used.
Disclaimer and references
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Titanium dioxide, also known as titanium(IV) oxide or titania, is the naturally occurring oxide of titanium, chemical formula TiO2.
Titanium dioxide occurs in four forms:
Pure titanium dioxide does not occur in nature but is derived from ilmenite or leuxocene ores. It is also readily mined in one of the purest forms, rutile beach sand.
Titanium dioxide is the most widely used white pigment because of its brightness and very high refractive index (n=2.4), in which it is surpassed only by diamond. When deposited as a thin film, its refractive index and color make it an excellent reflective optical coating for dielectric mirrors.
TiO2 is also an effective opacifier in powder form, where it is employed as a pigment to provide whiteness and opacity to products such as paints, coatings, plastics, papers, inks, foods, and most toothpastes. In cosmetic and skin care products, titanium dioxide is used both as a pigment and a thickener, and in almost every sunblock with a physical blocker, titanium dioxide is found both because of its refractive index and its resistance to discoloration under ultraviolet light. This advantage enhances its stability and ability to protect the skin from ultraviolet light. It is also used in resistance-type lambda probes (a type of oxygen sensor).
Titanium Dioxide, particularly in the anatase form, is a photocatalyst under ultraviolet light. The strong oxidative potential of the positive holes oxidizes water to create hydroxyl radicals. It can also oxidize oxygen or organic materials directly. Titanium dioxide is thus added to paints, cements, windows, tiles, or other products for sterilizing, deodorizing and anti-fouling properties. As TiO2 is exposed to UV light, it becomes increasingly hydrophilic, thus it can be used for anti-fogging coatings or self-cleaning windows. TiO2 incorporated into outdoor building materials can substantially reduce concentrations of airborne pollutants such as volatile organic compounds and NOx.
The Vinland map, the map of America ("Vinland") that was supposedly drawn during mid-15th century based on data from the Viking Age, has been declared a forgery on the basis that the ink on it contains traces of the TiO2-form anatase; TiO2 was not synthetically produced before the 1920s. Recently (1992) a counter-claim has been made that the compound can be formed from ancient ink.
External link
es:Dióxido de titanio
it:Diossido di titanio
nl:Titaanwit
ja:二酸化チタン
pl:Dwutlenek tytanu
ru:Титановые белила
sv:Titandioxid
zh:二氧化鈦
